Paul J. Toscano

Publications


  1. P. J. Toscano and L. G. Marzilli, "An Extensive Trans-Effect Series: The Reaction of Coordinated Trimethyl Phosphite", Inorg. Chem. 1979, 18, 421- 424.
  2. L. G. Marzilli, P. J. Toscano, L. Randaccio, N. Bresciani-Pahor, and M. Calligaris, "An Unusually Long Cobalt-Carbon Bond. Molecular Structure of trans-Bis(dimethylglyoximato)(isopropyl)(pyridine)cobalt(III). Implications with Regard to the Conformational Trigger Mechanism of Cobalt-Carbon Bond Cleavage in Coenzyme B12", J. Am. Chem. Soc. 1979, 101, 6754-6756.
  3. J. A. Kargol, R. W. Crecely, J. L. Burmeister, P. J. Toscano, and L. G. Marzilli, "Phosphorus-31 NMR Spectra of Cobaloximes: Influence of Electronic and Steric Effects of Axial Ligands", Inorg. Chim. Acta 1980, 40, 79-89.
  4. L. Randaccio, N. Bresciani-Pahor, P. J. Toscano, and L. G. Marzilli, "Structural and Spectroscopic Evidence that Cobalt to Carbon Bond Lengths Are Influenced by Conformational Effects in Cobaloximes. The Longest Co-C Bond in a Vitamin B12 Model: trans-Bis(dimethylglyoximato)(isopropyl)-(triphenylphosphine)cobalt(III)", J. Am. Chem. Soc. 1980, 102, 7372-7373.
  5. P. J. Toscano, C. C. Chiang, T. J. Kistenmacher, and L. G. Marzilli, "Synthesis and Solution and Solid-State Studies of Cobaloxime Complexes Containing Alkylated 6-Aminopurine Ligands. Molecular and Crystal Structure of the Complex with N(7)-Bound 3-Benzyladenine and Dimethyl Phosphonate as the Axial Ligands", Inorg. Chem. 1981, 20, 1513-1519.
  6. L. Randaccio, N. Bresciani-Pahor, P. J. Toscano, and L. G. Marzilli, "Bonding Mode and Trans Influence of the Nitromethyl Ligand. Structure of trans-Bis(dimethylglyoximato)(nitromethyl)(pyridine)cobalt(III)", Inorg. Chem. 1981, 20, 2722-2724.
  7. L. Randaccio, N. Bresciani-Pahor, P. J. Toscano, and L. G. Marzilli, "Angular Distortions at the Carbon Bound to Cobalt in Coenzyme B12 Models. Implications with Regard to Co-C Bond Cleavage in Coenzyme B12 and Other Alkylcobalamins", J. Am. Chem. Soc. 1981, 103, 6347-6351.
  8. L. G. Marzilli, P. J. Toscano, J. H. Ramsden, L. Randaccio, and N. Bresciani-Pahor, "Cobaloximes Containing Phosphorus-Donor Ligands", from Advances in Chemistry Series, 1982, 196, 85-99; "Catalytic Aspects of Metal Phosphine Complexes", E. C. Alyea and D. W. Meek (eds.).
  9. N. Bresciani-Pahor, L. Randaccio, P. J. Toscano, A. C. Sandercock, and L. G. Marzilli, "Steric Influences of Phosphorus-Donor Ligands on the Structure and Ligand-Exchange Rates of Cobaloximes", J. Chem. Soc., Dalton Trans. 1982, 129-134.
  10. N. Bresicani-Pahor, L. Randaccio, P. J. Toscano, and L. G. Marzilli, "Distortions Induced by Electronic and Steric Properties of Axial Ligands in Pseudo-Octahedral Cobaloximes. Crystal and Molecular Structures of trans-Bis(dimethylglyoximato)neopentyl(triphenylphosphine)cobalt(III) and trans-Aquabis(dimethylglyoximato)neopentylcobalt(III)", J. Chem. Soc., Dalton Trans. 1982, 567-572.
  11. N. Bresciani-Pahor, M. Calligaris, L. Randaccio, and P. J. Toscano, "Structural Aspects of a Vitamin B12 Model. The Crystal and Molecular Structure of trans-Cyanobis(dimethylglyoximato)(trimethyl phosphite)-cobalt(III)", J. Chem. Soc., Dalton Trans. 1982, 1009-1011.
  12. N. Bresciani-Pahor, L. Randaccio, and P. J. Toscano, "On the Correlation Between Bond Lengths, NMR Chemical Shifts and Cone Angles in Octahedral Cobaloximes Containing P-Donor Ligands. Crystal Structure of trans-Bis(dimethylglyoximato)(chloro)(phosphite)cobalt(III) Complexes with Phosphite = P(OMe)2Ph and P(OMe)Ph2", J. Chem. Soc., Dalton Trans. 1982, 1559-1563.
  13. N. Bresciani-Pahor, L. Randaccio, M. Summers, and P. J. Toscano, "Structural Distortions in Alkylcobaloximes Containing Triphenylphosphine as Axial Ligand. The X-ray Structures of trans-Bis(dimethylglyoximato)(bromomethyl)-(triphenylphosphine)cobalt(III) and trans-Bis(dimethylglyoximato)-(cyanomethyl)(triphenylphosphine)cobalt(III)", Inorg. Chim. Acta 1983, 68, 69-74.
  14. L. G. Marzilli, P. J. Toscano, M. Summers, L. Randaccio, N. Bresciani-Pahor, J. P. Glusker, and M. Rossi, "Co-C Bond Cleavage in B12 Systems and Organocobalt Compounds: The Role of Structure", Inorg. Chim. Acta 1983, 79, 29 (Abstract B28).
  15. M. F. Summers, P. J. Toscano, N. Bresciani-Pahor, G. Nardin, L. Randaccio, and L. G. Marzilli, "A Very Long Cobalt to Nitrogen Bond in a Coenzyme B12 Model. Relevance to the Role of the 5,6-Dimethylbenzimidazole in Co-C Bond Cleavage in Coenzyme B12", J. Am. Chem. Soc. 1983, 105, 6259-6263.
  16. P. J. Toscano and L. G. Marzilli, "Cobalt(III) Complexes of Stereospecific Linear NSNN Tetradentate Ligands. 1. Synthesis of Ligands that Adopt the Cis-b Coordination Geometry", Inorg. Chem. 1983, 22, 3342-3350.
  17. P. J. Toscano, T. F. Swider, L. G. Marzilli, N. Bresciani-Pahor, and L. Randaccio, "Organocobalt B12 Models. An Assessment of the Cis Effect Using Bis(glyoximato) as a Sterically Minimal Equatorial Atom Set. Structures of trans-Bis(glyoximato)methyl(L)cobalt(III) with L = Triphenylphosphine and Trimethyl Phosphite", Inorg. Chem. 1983, 22, 3416-3421.
  18. Paul J. Toscano and L. G. Marzilli, "B12 and Related Organocobalt Chemistry: Formation and Cleavage of Cobalt-Carbon Bonds", Prog. Inorg. Chem. 1984, 31, 105-204.
  19. N. Bresciani-Pahor, L. G. Marzilli, L. Randaccio, P. J. Toscano, and E. Zangrando, "Structural Determination of a Cobalt(III) Complex with a Co to Tertiary Carbon Bond: How Long Can a Co-C Bond Be?", J. Chem. Soc., Chem. Commun. 1984, 1508-1510.
  20. N. Bresciani-Pahor, L. Randaccio, E. Zangrando, and P. J. Toscano, "Organocobalt B12 Models. Structure of trans-Bis(glyoximato)(alkyl)-(pyridine)cobalt(III), with Alkyl = Me, Et, i-Pr", Inorg. Chim. Acta 1985, 96, 193-198.
  21. M.-Y. He, G. Xiong, P. J. Toscano, R. L. Burwell, Jr., and T. J. Marks, "Supported Organoactinides. Surface Chemistry and Catalytic Properties of Alumina-Bound (Cyclopentadienyl)- and (Pentamethylcyclopentadienyl)thorium and -uranium Hydrocarbyls and Hydrides", J. Am. Chem. Soc. 1985, 107, 641-652.
  22. P. J. Toscano and T. J. Marks, "Supported Organoactinides. High-Resolution Solid-State 13C NMR Studies of Catalytically Active, Alumina-Bound (Pentamethylcyclopentadienyl)thorium Methyl and Hydride Complexes", J. Am. Chem. Soc. 1985, 107, 653-659.
  23. P. J. Toscano and T. J. Marks, "Electrically Conductive Polymers Composed of Cofacially Joined Metallomacrocycles. Studies of Architecture and Electronic Structure in Phthalocyanine Materials by High Resolution Solid State NMR", Mol. Cryst. Liq. Cryst. 1985, 118, 337-344.
  24. L. Randaccio, N. Bresciani-Pahor, J. D. Orbell, M. Calligaris, M. F. Summers, B. Snyder, P. J. Toscano, and L. G. Marzilli, "Correlation of Rate, Spectroscopic, and Structural Data for (Pyridine)- or (Triphenylphosphine)-bis(dimethylglyoximato)organocobalt Complexes", Organometallics 1985, 4, 469-478.
  25. M. Rossi, J. P. Glusker, L. Randaccio, M. F. Summers, P. J. Toscano, and L. G. Marzilli, "The Structure of a B12 Coenzyme: Methylcobalamin Studies by X-ray and NMR Methods", J. Am. Chem. Soc. 1985, 107, 1729-1738.
  26. N. Bresciani-Pahor, M. Calligaris, L. Randaccio, L. G. Marzilli, M. F. Summers, P. J. Toscano, J. Grossman, and D. Liotta, "The 2,2,2-Trifluoroethyl Ligand: A Structural 'Reporter' Group for Its Carbanion Character in Organometallic Compounds", Organometallics 1985, 4, 630-636.
  27. N. Bresciani-Pahor, M. Forcolin, L. G. Marzilli, L. Randaccio, M. F. Summers, and P. J. Toscano, "Organocobalt B12 Models: Axial Ligand Effects on the Structural and Coordination Chemistry of Cobaloximes", Coord. Chem. Rev. 1985, 63, 1-125.
  28. P. J. Toscano and T. J. Marks, "Electrically Conductive Metallomacrocyclic Assemblies. High Resolution Solid-State NMR Spectroscopy as a Probe of Local Architecture and Electronic Structure in Phthalocyanine Molecular and Macromolecular 'Metals'", J. Am. Chem. Soc. 1986, 108, 437-444.
  29. P. J. Toscano and T. J. Marks, "A High-Resolution Solid-State 13C NMR Study of Fe(C5H5)(CO)2CH3/Alumina Surface Chemistry", Organometallics 1986, 5, 400-402.
  30. P. J. Toscano and T. J. Marks, "[(CH3)5C5]2Th(CH3)2/Silica Surface Chemistry. High-Resolution 13C CPMAS NMR Evidence for Alkylation of Surface Silicon Sites", Langmuir 1986, 2, 820-823.
  31. P. J. Toscano, A. L. Seligson, M. T. Curran, A. T. Skrobutt, and D. C. Sonnenberger, "Cobalt-Carbon Bond Disruption Enthalpies: The First Reliable Measurement of a Co-Methyl BDE via Solution Thermochemical Methods", Inorg. Chem. 1989, 28, 166-168.
  32. P. J. Toscano and E. Barren, "The Reaction of Bis(dimethylglyoximato)-(pyridine)cobalt(I) Anion with CF2=CFX (X = Cl or Br): Evidence for Competitive Reaction Paths", J. Chem. Soc., Chem. Commun. 1989, 1159-1160.
  33. P. J. Toscano, E. Barren, and A. L. Seligson, "Iodinolysis of the Co-C Bond in trans-Bis(dimethylglyoximato)alkyl(4-cyanopyridine)cobalt(III) Complexes: Evidence for a Bimolecular Oxidative Mechanism", Organometallics 1989, 8, 2085-2088.
  34. P. J. Toscano, L. Konieczny, S. Liu, and J. Zubieta, "The Convenient Preparation and the Molecular Structure of trans-Bis(dimethylglyoximato)-(trifluoromethyl)(pyridine)cobalt(III): A Cobaloxime with a Very Short Co-C(sp3) Bond", Inorg. Chim. Acta 1989, 166, 163-165.
  35. P. J. Toscano, K. A. Belsky, L. M. Engelhardt, K. J. Fordon, and A. H. White, "Improved Synthesis and Isolation of a Flexible Linear NSNN Tetradentate Ligand and the Crystal Structure of Its Stereospecific Dinitrocobalt(III) Complex", Inorg. Chem. 1990, 29, 1357-1359.
  36. P. J. Toscano, K. J. Fordon, L. M. Engelhardt, B. W. Skelton, A. H. White, and P. A. Marzilli, "The Synthesis and Isolation of the Stereospecific Ligand, N-(2-Aminoethyl)-2-[(2-aminoethyl)thio]acetamide (egeH). Comparison of the Crystal Structure of Co(ege)(NO2)2]·4H2O with Related Systems", Polyhedron 1990, 9, 1079-1085.
  37. P. J. Toscano, H. Brand, S. Liu, and J. Zubieta, "Cobalt Complexes with Bulky Perfluorinated Alkyl Ligands. Synthesis, Characterization, and Molecular Structure of trans-Bis(dimethylglyoximato)(pyridine)(F-isopropyl)-cobalt(III)", Inorg. Chem. 1990, 29, 2101-2105.
  38. P. J. Toscano, K. J. Fordon, D. Macherone, S. Liu, and J. Zubieta, "Novel Square Pyramidal Copper(II) Complexes of the tereospecific Linear NSNN Tetradentate Ligand, N-[(2-Pyridyl)methyl]-2-[(2-aminoethyl)thio]acetamide (pygeH). The Crystal Structures of [Cu(pyge)X], (X = Br, N3)", Polyhedron 1990, 9, 2375-2383.
  39. A. E. Kaloyeros, P. J. Toscano, R. B. Rizk, V. Tulchinsky, and A. Greene, "Low Temperature Metal Organic Chemical Vapor Deposition (LTMOCVD) of Electronic Materials", Mater. Res. Soc., Symp. Proc. (Diamond, Silicon Carbide and Related Wide Bandgap Semiconductors) 1990, 162, 409-414.
  40. A. E. Kaloyeros, J. W. Corbett, P. J. Toscano, and R. B. Rizk, "The Low-Temperature Metal-Organic Chemical Vapor Deposition (LTMOCVD) Route to Amorphous Silicon Semiconductors", Mater. Res. Soc., Symp. Proc. (Amorphous Silicon Technology-1990) 1990, 192, 601-606.
  41. P. J. Toscano and H. L. Frisch, "Sorption of Small Molecules in Polymeric Media Studied via High-Resolution Solid-State NMR Spectroscopy", Proceedings of the 1990 U.S. Army CRDEC Scientific Conference on Chemical Defense Research 1990, 941-947.
  42. P. J. Toscano, H. Brand, S. Geremia, L. Randaccio, and E. Zangrando, "Evidence for Steric Trans Influences and Effects in Perfluoroisopropyl Cobaloximes. Molecular Structure of trans-Bis(dimethylglyoximato)-(triphenylphosphine)(perfluoroisopropyl)cobalt(III)", Organometallics 1991, 10, 713-720.
  43. P. J. Toscano, K. A. Belsky, T.-C. Hsieh, T. Nicholson, and J. Zubieta, "Synthesis, Characterization, and Stereochemical Preferences of Cobalt(III) Ternary Amino Acid Complexes Containing N-((2-Pyridyl)methyl)-2-((2- aminoethyl)thio)acetamide, a Stereospecific Linear NSNN Tetradentate Ligand", Polyhedron 1991, 10, 977-991.
  44. P. J. Toscano and H. L. Frisch, "Dual Mode Sorption of Tri-n-Butyl Phosphate in Polystyrene Studied via High-Resolution Solid-State 31P NMR Spectroscopy", J. Polym. Sci. Polym. Chem. Ed. 1991, 29, 1219-1221.
  45. P. J. Toscano, E. J. Schermerhorn, C. Dettelbacher, D. A. Macherone, and J. Zubieta, "Monomeric Four-coordinate Vanadium(V) Oxo Complexes Containing a Labile Ligand: Synthesis and X-Ray Structural Characterization of [(C23H30O2)V(O)Cl]", J. Chem. Soc., Chem. Commun. 1991, 933-934.
  46. P. J. Toscano, E. J. Schermerhorn, J. Waechter, P. Zhou, and H. L. Frisch, "Diffusion of Small Fluorinated Molecules in Polymeric Media Studied via High-Resolution Solid-State 19F NMR Spectroscopy", Proceedings of the 1991 U.S. Army CRDEC Scientific Conference on Chemical Defense Research 1991, 831-837.
  47. A. E. Kaloyeros, C. Dettelbacher, E. T. Eisenbraun, W. A. Lanford, H. Li, J. F. Olowolafe, S. Murarka, F. Pintchovski, Y.-T. Shy, and P. J. Toscano, "The Effect of Grain Boundaries and Substrate Interactions with Hydrogen on the CVD Growth of Device-Quality Copper", Mater. Res. Soc., Symp. Proc. (Structure/Property Relationships for Metal/Metal Interfaces) 1991, 229, 123-128.
  48. M. I. Khan, J. Zubieta, and P. Toscano, "Protonation Sites in a Heteropolyvanadate of Phosphorus: X-ray Crystal Structure of (Me3NH)4(NH4)[H4PV14O42]", Inorg. Chim. Acta 1992, 193, 17-20.
  49. K. D. Karlin, Z. Tyekl r, A. Farooq, M. S. Haka, P. Ghosh, R. W. Cruse, Y. Gultneh, J. C. Hayes, P. J. Toscano, and J. Zubieta, "Dioxygen-Copper Reactivity and Functional Modeling of Hemocyanins. Reversible Binding of O2 and CO to Dicopper(I) Complexes [CuI2(L)]2+ (L = Dinucleating Ligand) and the Structure of a Bis(Carbonyl) Adduct, [CuI2(L)(CO)2]2+", Inorg. Chem. 1992, 31, 1436-1451.
  50. E. T. Eisenbraun, B. Zheng, H. Li, A. Wax, A. E. Kaloyeros, C. Dettelbacher, P. J. Toscano, N. Devashrayee, S. P. Murarka, J. F. Olowolafe, and F. Pintchovski, "Selective and Blanket Low-Temperature Copper CVD for Multilevel Metallization in ULSI", Advanced Metallization for ULSI Applications, Conference Proceedings; V. V. S. Rana, R. V. Joshi, and I. Ohdomari, Eds.; MRS: Pittsburgh, PA; 1992, 397-401.
  51. P. J. Toscano, H. Brand, and P. T. DiMauro, "Synthesis, Characterization, and Reactivity of Novel Organochromium(III) Porphyrin Complexes", Organometallics 1993, 12, 30-35.
  52. P. J. Toscano, J. Waechter, E. J. Schermerhorn, P. Zhou, and H. L. Frisch, "High-Resolution Solid-State 19F NMR Spectroscopy of the Sorption and Diffusion of Fluorine-Containing Aromatic Molecules in Polymeric Media", J. Polym. Sci. Polym. Chem. Ed. 1993, 31, 859-863.
  53. P. J. Toscano, K. A. Belsky, T. Nicholson, and J. Zubieta, "Cobalt(III) Complexes of Stereospecific Linear NSNN Tetradentate Ligands. Synthesis and Characterization of Ternary Amino Acid Complexes Containing Tetradentate Ligands with Terminal Amine Donors", Inorg. Chim. Acta 1993, 206, 77-83.
  54. E. Eisenbraun, B. Zheng, J. Liu, A. Wax, C. Dettelbacher, P. J. Toscano, S. P. Murarka, R. Fiordalice, F. Pintchovski, and A. E. Kaloyeros, "CVD of Copper from Copper(II) b-Diketonates Using A New Liquid Delivery Approach", Advanced Metallization for ULSI Applications 1992, Conference Proceedings; T. S. Cale and F. S. Pintchovski, Eds.; MRS: Pittsburgh, PA; 1993, 107-113.
  55. J. Faltermeier, E. Eisenbraun, J. Liu, C. Dettelbacher, P. J. Toscano, B. Arkles, and A. E. Kaloyeros, "MOCVD of Tungsten for Multilevel Interconnects", Advanced Metallization for ULSI Applications 1992, Conference Proceedings; T. S. Cale and F. S. Pintchovski, Eds.; MRS: Pittsburgh, PA; 1993, 267-272.
  56. B. Zheng, E. T. Eisenbraun, P. J. Toscano, S. P. Murarka, A. E. Kaloyeros, "In-Situ Quadrupole Mass Spectrometry and Fourier Transform Infrared Spectroscopy Studies of Gas Phase Chemistry in CVD of Copper", Proceedings of TECHCON '93 1993, 378-380.
  57. K. Araki, W. Q. Yun, J. O'Toole, P. J. Toscano, and J. T. Welch, "The Synthesis of 2,3-Dideoxy-2-fluoro-3-C-methylpentose-Containing Nucleosides via [3,3]-Sigmatropic Rearrangements", Carbohydr. Res. 1993, 249, 139-161.
  58. K. T. Potts, C. P. Horwitz, A. Fessak, M. Keshavarz-K, K. E. Nash, and P. J. Toscano, "Coordination of Ethynylpyridine Ligands with Cu(I): X-ray Structure of a Novel, Triple-Helical, Tricuprous Complex", J. Am. Chem. Soc. 1993, 115, 10444-10445.
  59. J. T. Welch, E. M. Keskeny, and P. J. Toscano, "A Novel Approach to the Preparation of entacarbonyl(dialkylaminofluorocarbene)chromium Compounds. Confirmation of Structure by Single Crystal X-ray Diffraction", J. Organomet. Chem. 1993, 461, 95-97.
  60. P. J. Toscano, P. T. DiMauro, S. Geremia, L. Randaccio, E. Zangrando, "The Synthesis and Crystal Structure of Cr(acacen)py2][ZnCl3py]", Inorg. Chim. Acta 1994, 217, 195-199.
  61. P. J. Toscano, E. Barren, H. Brand, L. Konieczny, E. J. Schermerhorn, K. Shufon, and S. van Winkler, "Synthetic, Structural, and Reactivity Studies of Organocobalt(III) Compounds Containing Fluorinated Alkyl Ligands", ACS Symp. Ser. 1994, 555, 286-296; "Inorganic Fluorine Chemistry: Toward the 21st Century", J. S. Thrasher and S. H. Strauss (eds.).
  62. I. Lou, L. Chen, E. T. Eisenbraun, E. J. Schermerhorn, P. J. Toscano, M. E. Thomas, B. Arkles, and A. E. Kaloyeros, "Plasma-Assisted Chemical Vapor Deposition of Gold for ULSI Multilevel Metallization Schemes", Advanced Metallization for ULSI Applications 1993, Conference Proceedings; D. P. Favreau, Y. Shacham-Diamand, and Y. Horiike, Eds.; MRS: Pittsburgh, PA; 1994, 569-573.
  63. E. Block, C. Guo, M. Thiruvazhi, and P. J. Toscano, "Total Synthesis of Thiarubrine B, 3-(3-Buten-1-ynyl)-6-(1,3-pentadiynyl)-1,2-dithiin, the Antibiotic Principle of Giant Ragweed (Ambrosia trifida)", J. Am. Chem. Soc. 1994, 116, 9403-9404.
  64. W. E. Broderick, D. M. Eichhorn, X. Liu, P. J. Toscano, S. M. Owens, and B. M. Hoffman, "Three Phases of [Fe(C5Me5)2]+[TCNQ]-: Ferromagnetism in a New Structural Phase", J. Am. Chem. Soc. 1995, 117, 3641-3642.
  65. J. Okuda, K. E. du Plooy, and P. J. Toscano, "Synthesis and Characterization of Titanium Complexes Containing the 1-(3-Butenyl)-2,3,4,5-tetramethyl-cyclopentadienyl Ligand", J. Organomet. Chem. 1995, 495, 195-202.
  66. B. Zheng, C. Goldberg, E. T. Eisenbraun, J. Liu, A. E. Kaloyeros, P. J. Toscano, S. P. Murarka, J. F. Loan, and J. Sullivan, "In Situ Quadrupole Mass Spectroscopy Studies of Water and Solvent Coordination to Copper(II) b- Diketonate Precursors: Implications for the Chemical Vapor Deposition of Copper", Mater. Chem. Phys. 1995, 41, 173-181.
  67. Z. Madarász, I. Németh, P. Toscano, J. Welch and J. Nyitrai, "Stereocontrolled Synthesis of Methyl aR,2S,3R-3-(1-Acetoxy-ethyl)-1- (4-methoxyphenyl)-4-oxoazetidine-2-carboxylate", Tetrahedron Lett. 1995, 36, 8303-8306.
  68. W. E. Broderick, X. Liu, S. Owens, P. J. Toscano, D. M. Eichhorn, and B. M. Hoffman, "Ferromagnetism in a New Structural Phase of [Fe(C5Me5)2][TCNQ]", Mol. Cryst. Liq. Cryst. Sci. Technol., Sect. A 1995, 273, 455-458.
  69. E. Block, M. Thiruvazhi, P. J. Toscano, T. Bayer, S. Grisoni, and S.-H. Zhao, "Allium Chemistry: Structure, Synthesis, Natural Occurrence in Onion (Allium cepa), and Reactions of 2,3-Dimethyl-5,6-dithiabicyclo[2.1.1]hexane S-Oxides", J. Am. Chem. Soc. 1996, 118, 2790-2798.
  70. P. J. Toscano, C. Dettelbacher, J. Waechter, N. P. Pavri, D. H. Hunt, E. T. Eisenbraun, B. Zheng, and A. E. Kaloyeros, "Synthesis and Characterization of Polyfluorinated b-Diketonate Transition Metal Complexes", J. Coord. Chem. 1996, 38, 319-335.
  71. S. C. Ngo, J. Okuda, P. Toscano, and J. T. Welch, "Bistriflate Titanium Complexes for the Polymerization of Styrene", Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1996, 37, 331-332.
  72. E. Block, R. S. Glass, R. DeOrazio, D. L. Lichtenberger, J. R. Pollard, E. E. Russell, T. B. Schroeder, M. Thiruvazhi, and P. J. Toscano, "Significant Intramolecular Sulfur-Sulfur Interactions in cis- and trans-2,3-Dimethyl-5,6-dithiabicyclo[2.1.1]hexane", Synlett 1997, 525-528.
  73. P. J. Toscano, "Oxidative Additions and Reductive Eliminations to Compounds of the Transition Elements; Section 10.3.2: Reactions at a Group IIIA or IVA Metal Center", in Inorganic Reactions and Methods, J. D. Atwood (Ed.), VCH Publishers, New York; 1998, 14, 193-204.
  74. P. J. Toscano, "Oxidative Additions and Reductive Eliminations to Compounds of the Transition Elements; Section 10.3.3: Reactions at a Group VA Metal Center", in Inorganic Reactions and Methods, J. D. Atwood (Ed.), VCH Publishers, New York; 1998, 14, 204-215.
  75. P. J. Toscano, "Oxidative Additions and Reductive Eliminations to Compounds of the Transition Elements; Section 10.3.4: Reactions at a Group VIA Metal Center", in Inorganic Reactions and Methods, J. D. Atwood (Ed.), VCH Publishers, New York; 1998, 14, 215-227.
  76. P. J. Toscano, E. J. Schermerhorn, E. Barren, S. Liu, and J. Zubieta, "Synthesis, Characterization, and Reactivity of Monomeric Titanium Complexes Containing a Chelating Bis(phenolate) Ligand", J. Coord. Chem. 1998, 43, 169-185.
  77. J. Lin, P. J. Toscano, and J. T. Welch, "Inhibition of Dipeptidyl Peptidase IV by Fluoroolefin-Containing N-Peptidyl-O-hydroxylamine Peptidomimetics", Proc. Nat. Acad. Sci. 1998, 95, 14020-14024.
  78. J. W. Canary, C. S. Allen, J. M. Castagnetto, Y.-H. Chiu, P. J. Toscano, and Y. Wang, "Solid State and Solution Characterization of Chiral, Conformationally Mobile Tripodal Ligands", Inorg. Chem. 1998, 37, 6255-6262.
  79. S. D. Kohl, P. J. Toscano, W. Hou, and J. A. Rice, "Solid-State 19F NMR Investigation of Hexafluorobenzene Sorption to Soil Organic Matter", Environ. Sci. Technol. 2000, 34, 204-210.
  80. S. D. Kohl, P. J. Toscano, and J. A. Rice, "Solid-State NMR Investigation of Dual-Mode Sorption to Soil Organic Matter"; Prepr. Ext. Abstr. ACS Natl. Meet., Am. Chem. Soc., Div. Environ. Chem. 2000, 40, 110-112.
  81. E. Block, M. Birringer, W. Jiang, T. Nakahodo, H. J. Thompson, P. J. Toscano, H. Uzar, X. Zhang, and Z. Zhu, "Allium Chemistry: Synthesis, Natural Occurrence, Biological Activity, and Chemistry of Se-Alk(en)ylselenocysteines and Their g-Glutamyl Derivatives and Oxidation Products", J. Agric. Food Chem. 2001, 49, 458-470.
  82. R. U. Claessen, J. T. Welch, P. J. Toscano, K. K. Banger, A. M. Kornilov, E. T. Eisenbraun, and A. E. Kaloyeros, "The 2,2,6,6-Tetramethyl-2-sila-3,5-heptanedione Route to the Chemical Vapor Deposition of Copper for Gigascale Interconnect Applications", Mater Res. Soc., Symp. Proc. (Materials, Technology and Reliability for Advanced Interconnects and Low-k Dielectrics), 2001, 612, D6.8.1-D6.8.6.
  83. K. K. Banger, A. Kornilov, R. U. Claessen, E. T. Eisenbraun, A. E. Kaloyeros, P. J. Toscano, and J. T. Welch, "The First Metal Complex Containing a Silylated b-Diketonate Ligand: Bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato)copper(II)", Inorg. Chem. Commun. 2001, 4, 496-500.
  84. K. K. Banger, C. Birringer, R. U. Claessen, P. Lim, P. J. Toscano, and J. T. Welch, "A Facile Synthesis of 2,2,6,6-Tetramethyl-2-germa-3,5-heptanedione: The Preparation and Characterization of the First Germa-b-diketonate Copper(II) Complex", Organometallics 2001, 20, 4745-4748.
  85. S. C. Ngo, K. K. Banger, P. J. Toscano, and J. T. Welch, "Synthesis and Physical and Structural Characterization of Ag(I) Complexes Supported by Non-fluorinated b-Diketonate and Related Ancillary Ligands", Polyhedron, 2002, 21, 1289-1297.
  86. M. J. DelaRosa, K. S. Bousman, J. T. Welch, and P. J. Toscano, "Physical and Structural Characterization of Ce(IV) b-Diketonate Complexes: Evidence for Geometrical Isomers in the Solid-State", J. Coord. Chem. 2002, 55, 781-793.
  87. S. C. Ngo, P. J. Toscano, and J. T. Welch, "Preparation and Characterization of Half-Sandwich (Pentamethylcyclopentadienyl)(triflato)titanium(IV) Complexes: Solid-State Structural Motifs and Catalysis Studies", Helv. Chim. Acta 2002, 85, 3366-3382.
  88. E. Block, F. Tries, C. He, C. Guo, M. Thiruvazhi, and P. J. Toscano, "Perthio- and Perseleno-1,3-butadienes, -but-1-ene-3-ynes and –[3]- cumulenes: One Step Syntheses from 1,4-Dilithio-1,3-butadiyne", Org. Lett. 2003, 5, 1325-1327.
  89. S. C. Ngo, K. K. Banger, M. J. DelaRosa, P. J. Toscano, and J. T. Welch, "Thermal and Structural Characterization of a Series of Homoleptic Cu(II) Dialkyldithiocarbamate Complexes: Bigger is Only Marginally Better for Potential MOCVD Performance", Polyhedron 2003, 22, 1575-1583.
  90. K. K. Banger, S. C. Ngo, S. Higashiya, R. U. Claessen, K. S. Bousman, P. N. Lim, P. J. Toscano, and J. T. Welch, "Facile Synthesis of a Novel Class of Organometalloid-containing Ligands, the Sila-b-diketones: Preparation and Physical and Structural Characterization of the Copper(II) Complexes, Cu[R'C(O)CHC(O)SiR3]2", J. Organomet. Chem. 2003, 678, 15-32.
  91. S. Higashiya, K. K. Banger, S. C. Ngo, P. N. Lim, P. J. Toscano, and J. T. Welch, "Synthesis of Fluorinated a-Sila-b-Diketones and Their Cu(II) Complexes", Inorg. Chim. Acta 2003 351, 291-304.
  92. P. J. Toscano, L. Lettko, E. J. Schermerhorn, J. Waechter, and K. Shufon, S. Liu, E. V. Dikarev, and J. Zubieta, "Synthesis and Characterization of Diphenylglyoximato Cobalt(III) Complexes. The Molecular Structures of trans-Bis(diphenylglyoximato)(alkyl)(pyridine)cobalt(III), with Alkyl = CH2CMe3, CH2SiMe3, and CF3", Polyhedron 2003, 22, 2809-2820.
  93. M. J. DelaRosa, K. K. Banger, S. Higashiya, S. C. Ngo, D. H. Hunt, K. S. Bousman, P. J. Toscano, and J. T. Welch, "Structural Investigations of Copper(II) Complexes Containing Fluorine-substituted ß-Diketonate Ligands", J. Fluorine Chem., 2003, 123, 109-117.
  94. M. J. DelaRosa, K. S. Bousman, J. T. Welch, and P. J. Toscano, "Structural Investigations of Copper(II) Complexes Containing Unsymmetrical ß-Diketonate and Monothio-ß-diketonate Ligands", J. Coord. Chem. 2003, 56, 1339-1349.
  95. R. U. Claessen, A. M. Kornilov, K. K. Banger, S. C. Ngo, S. Higashiya, C. C. Wells, E. V. Dikarev, P. J. Toscano, and J. T. Welch, "Investigations Into the Preparation of Sila-ß-diketones via 2-Trimethylsilyl-1,3- dithianes: Structural Characterization of a Second Polymorph of Bis(2,2,6,6-tetramethyl-2-sila-3,5-heptanedionato)copper(II)", J. Organomet. Chem. 2004, 689, 71-81.
  96. S. Higashiya, W. J. Chung, D. S. Lim, S. C. Ngo, W. H. Kelly IV, P. J. Toscano, and J. T. Welch, "Synthesis of Mono- and Difluoroacetyl- trialkylsilanes and the Corresponding Enol Silyl Ethers", J. Org. Chem. 2004, 69, 6323-6328.
  97. K. S. Bousman, J. T. Welch, and P. J. Toscano, "The Effect of Sulfur on CVD Performance of Pd(II) ß-Diketonate Precursors and the Completion of a Structural trans-Influence Series: Synthesis and Structural Characterization of Pd(S,S-tmhd)2", Inorg. Chim. Acta 2004, 357, 3871-3876.
  98. K. M. Beketov, J. T. Welch, P. Toscano, L. A. Kayukova, A. L. Akhelova, and K. D. Praliev, "Crystal and Molecular Sructure of ß-Piperidinopropio- amidoxime Monochloroacetate and Hydrochlorides of Its O-Benzoylation Products", J. Struct. Chem. 2004, 45, 509-517.